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A novel strategy for the construction of silk fibroin–SiO composite aerogel with enhanced mechanical

《化学科学与工程前沿(英文)》 2023年 第17卷 第3期   页码 288-297 doi: 10.1007/s11705-022-2222-7

摘要: The practical application of silica aerogels is an enormous challenge due to the difficulties in improving both mechanical property and thermal insulation performance. In this work, silk fibroin was used as scaffold to improve the mechanical property and thermal insulation performance of silica aerogels. The ungelled SiO2 precursor solution was impregnated into silk fibroin to prepare silk fibroin–SiO2 composite aerogels via sol−gel method followed by freeze-drying. By virtue of the interfacial hydrogen-bonding interactions and chemical reactions between silk fibroin and silica nanoparticles, SiO2 was well-dispersed in the silk fibroin aerogel and composite aerogels exhibited enhanced mechanical property. By increasing the loading of silk fibroin from 15 wt % to 21 wt %, the maximum compressive stress was enhanced from 0.266 to 0.508 MPa when the strain reached 50%. The thermal insulation performance of the composite aerogels was improved compared with pure silica aerogel, as evidenced that the thermal conductivity was decreased from 0.0668 to 0.0341 W∙m‒1∙K‒1. Moreover, the composite aerogels exhibited better hydrophobicity and fire retardancy compared to pure silica aerogel. Our work provides a novel approach to preparing silk fibroin–SiO2 composite aerogels with enhanced mechanical property and thermal insulation performance, which has potential application as thermal insulation material.

关键词: silica aerogel     silk fibroin     impregnation     thermal insulation     mechanical property    

Precast steel–UHPC lightweight composite bridge for accelerated bridge construction

Shuwen DENG, Xudong SHAO, Xudong ZHAO, Yang WANG, Yan WANG

《结构与土木工程前沿(英文)》 2021年 第15卷 第2期   页码 364-377 doi: 10.1007/s11709-021-0702-3

摘要: In this study, a fully precast steel–ultrahigh performance concrete (UHPC) lightweight composite bridge (LWCB) was proposed based on Mapu Bridge, aiming at accelerating construction in bridge engineering. Cast-in-place joints are generally the controlling factor of segmental structures. Therefore, an innovative girder-to-girder joint that is suitable for LWCB was developed. A specimen consisting of two prefabricated steel–UHPC composite girder parts and one post-cast joint part was fabricated to determine if the joint can effectively transfer load between girders. The flexural behavior of the specimen under a negative bending moment was explored. Finite element analyses of Mapu Bridge showed that the nominal stress of critical sections could meet the required stress, indicating that the design is reasonable. The fatigue performance of the UHPC deck was assessed based on past research, and results revealed that the fatigue performance could meet the design requirements. Based on the test results, a crack width prediction method for the joint interface, a simplified calculation method for the design moment, and a deflection calculation method for the steel–UHPC composite girder in consideration of the UHPC tensile stiffness effect were presented. Good agreements were achieved between the predicted values and test results.

关键词: accelerated bridge construction     ultrahigh-performance concrete     steel–UHPC composite bridge     UHPC girder-to-girder joint    

Technological development and engineering applications of novel steel-concrete composite structures

Jianguo NIE, Jiaji WANG, Shuangke GOU, Yaoyu ZHU, Jiansheng FAN

《结构与土木工程前沿(英文)》 2019年 第13卷 第1期   页码 1-14 doi: 10.1007/s11709-019-0514-x

摘要:

In view of China’s development trend of green building and building industrialization, based on the emerging requirements of the structural engineering community, the development and proposition of novel resource-saving high-performance steel-concrete composite structural systems with adequate safety and durability has become a kernel development trend in structural engineering. This paper provides a state of the art review of China’s cutting-edge research and technologies in steel-concrete composite structures in recent years, including the building engineering, the bridge engineering and the special engineering. This paper summarizes the technical principles and applications of the long-span bi-directional composite structures, the long-span composite transfer structures, the comprehensive crack control technique based on uplift-restricted and slip-permitted (URSP) connectors, the steel plate concrete composite (SPCC) strengthen technique, and the innovative composite joints. By improving and revising traditional structure types, the comprehensive superiority of steel-concrete composite structures is well elicited. The research results also indicate that the high-performance steel-concrete composite structures have a promising popularizing prospect in the future.

关键词: high-performance composite structure     bi-directional composite     composite transfer     uplift-restricted and slip-permitted connectors     steel plate concrete composite strengthen    

Factors affecting photocatalytic performance through the evolution of the properties due to the phase transition from NaBiO·2HO to BiO

《能源前沿(英文)》 2022年 第16卷 第3期   页码 471-482 doi: 10.1007/s11708-021-0778-4

摘要: The phase transition process of a photocatalytic system from NaBiO3·2H2O to BiO2–x has been investigated to understand the important factors that affect photocatalytic performance in a composite system. It is found that a proper amount of BiO2–x on the surface of NaBiO3·2H2O could effectively suppress the electron/hole recombination and increase the exposed reactive sites for photocatalytic reaction. A fully covered BiO2–x on NaBiO3·2H2O results in a dramatical decrease of photocatalytic degradation of dye. An over long hydrothermal process can result in BiO2–x with reduced oxygen vacancies, which degrades the photocatalytic activity. Furthermore, the photocatalytic reduction ability of CO2 conversion has been investigated, indicating that the surface activity to different reactants also directly affects the catalytic performance. The investigation of the gradient phase transition process presents a clear guidance to construct a desired photocatalytic system, in addition to selecting gradient materials with suitable bandgap structure and a morphology with different fraction and distribution of each component. The defect evolution of each component during construction of a composite is also an important factor that should be optimized and considered in making a composite to achieve high photocatalytic efficiency.

关键词: composite construction     distribution     BiO2–x     evolution of defects    

Deep eutectic solvent inclusions for high- composite dielectric elastomers

《化学科学与工程前沿(英文)》 2022年 第16卷 第6期   页码 996-1002 doi: 10.1007/s11705-022-2138-2

摘要: Recent advances in novel electroactive devices have placed new requirements on material development. High-performance dielectric elastomers with good mechanical stretchability and high dielectric constant are under high demand. However, the current strategy for fabricating these materials suffers from high cost or low thermal stability, which greatly hinders large-scale industrial production. Herein, we have successfully developed a novel strategy for improving the dielectric constant of polymeric elastomers via deep eutectic solvent inclusion by taking advantage of the low cost, convenient and environmentally benign synthesis process and high ionic conductivity from deep eutectic solvents. The as-prepared composite elastomers showed good stretchability and a greatly enhanced dielectric constant with a negligible increase in dielectric dissipation. Moreover, we have proven the universality of our strategy by using different types of deep eutectic solvents. It is believed that low-cost, easy-synthesis and environmentally friendly deep eutectic solvents including composite elastomers are highly suitable for large-scale industrial production and can greatly broaden the application fields of dielectric elastomers.

关键词: composite materials     deep eutectic solvent     dielectric elastomer     high dielectric constant    

An antibiotic composite electrode for improving the sensitivity of electrochemically active biofilm biosensor

《环境科学与工程前沿(英文)》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1518-7

摘要:

• Antibiotic azithromycin employed in graphite electrode for EAB biosensor.

关键词: AZM@GP composite electrode     EAB-biosensor     Water quality early-warning    

Structural optimization of filament wound composite pipes

Roham RAFIEE; Reza SHAHZADI; Hossein SPERESP

《结构与土木工程前沿(英文)》 2022年 第16卷 第8期   页码 1056-1069 doi: 10.1007/s11709-022-0868-3

摘要: An optimization procedure is developed for obtaining optimal structural design of filament wound composite pipes with minimum cost utilized in pressurized water and waste-water pipelines. First, the short-term and long-term design constraints dictated by international standards are identified. Then, proper computational tools are developed for predicting the structural properties of the composite pipes based on the design architecture of layers. The developed computational tools are validated by relying on experimental analysis. Then, an integrated design-optimization process is developed to minimize the price as the main objective, taking into account design requirements and manufacturing limitations as the constraints and treating lay-up sequence, fiber volume fraction, winding angle, and the number of total layers as design variables. The developed method is implemented in various case studies, and the results are presented and discussed.

关键词: composite pipes     optimization     experimental validation     computational modeling     filament winding    

Progressive failure analysis of notched composite plate by utilizing macro mechanics approach

《结构与土木工程前沿(英文)》 2021年 第15卷 第3期   页码 623-642 doi: 10.1007/s11709-021-0726-8

摘要: In this study, gradual and sudden reduction methods were combined to simulate a progressive failure in notched composite plates using a macro mechanics approach. Using the presented method, a progressive failure is simulated based on a linear softening law prior to a catastrophic failure, and thereafter, sudden reduction methods are employed for modeling a progressive failure. This combination method significantly reduces the computational cost and is also capable of simultaneously predicting the first and last ply failures (LPFs) in composite plates. The proposed method is intended to predict the first ply failure (FPF), LPF, and dominant failure modes of carbon/epoxy and glass/epoxy notched composite plates. In addition, the effects of mechanical properties and different stacking sequences on the propagation of damage in notched composite plates were studied. The results of the presented method were compared with experimental data previously reported in the literature. By comparing the numerical and experimental data, it is revealed that the proposed method can accurately simulate the failure propagation in notched composite plates at a low computational cost.

关键词: progressive failure     notched composite plate     Hashin failure criterion     macro mechanics approach     finite element method    

Bending and rotational behaviour of semi-continuous composite beams

WANG Jingfeng, LI Guoqiang

《结构与土木工程前沿(英文)》 2008年 第2卷 第2期   页码 116-122 doi: 10.1007/s11709-008-0015-9

摘要: Stresses and deflections were measured in various semi-continuous composite beams. The bending and rotational capacities of the composite connections were measured in terms of beam curvatures and deflections by using two full-scale semi-rigid composite frames with monotonic loadings. The effect of semi-rigid connections on the performance of composite beams with various loadings was compared with predictions and codes. The tests show that the semi-continuous composite beams are more economic and effective than the simple or continuous composite beams. The semi-rigid connections affect the bending capacities and beam deflections, so the connection behavior should be considered in the design of composite beams. Yielding analysis of the steel beam bottom flange has some influence on the deflection calculation of composite beams.

关键词: rotational     effective     deflection calculation     semi-continuous composite     full-scale semi-rigid    

Experimental study on flexural behavior of ECC/RC composite beams with U-shaped ECC permanent formwork

Zhi QIAO, Zuanfeng PAN, Weichen XUE, Shaoping MENG

《结构与土木工程前沿(英文)》 2019年 第13卷 第5期   页码 1271-1287 doi: 10.1007/s11709-019-0556-0

摘要: To enhance the durability of a reinforced concrete structure, engineered cementitious composite (ECC), which exhibits high tensile ductility and good crack control ability, is considered a promising alternative to conventional concrete. However, broad application of ECC is hindered by its high cost. This paper presents a new means to address this issue by introducing a composite beam with a U-shaped ECC permanent formwork and infill concrete. The flexural performance of the ECC/RC composite beam has been investigated experimentally with eight specimens. According to the test results, the failure of a composite beam with a U-shaped ECC formwork is initiated by the crushing of compressive concrete rather than debonding, even if the surface between the ECC and the concrete is smooth as-finished. Under the same reinforcement configurations, ECC/RC composite beams exhibit increases in flexural performance in terms of ductility, load-carrying capacity, and damage tolerance compared with the counterpart ordinary RC beam. Furthermore, a theoretical model based on the strip method is proposed to predict the moment-curvature responses of ECC/RC composite beams, and a simplified method based on the equivalent rectangular stress distribution approach has also evolved. The theoretical results are found to be in good agreement with the test data.

关键词: engineered cementitious composite (ECC)     durability     ECC/RC composite beam     permanent formwork     flexural performance     theoretical method    

Bending performance of composite bridge deck with T-shaped ribs

Qingtian SU, Changyuan DAI, Xu JIANG

《结构与土木工程前沿(英文)》 2019年 第13卷 第4期   页码 990-997 doi: 10.1007/s11709-019-0532-8

摘要: This paper proposes a new type of steel-concrete composite deck, which is composed of orthotropic steel deck (OSD) with T-shaped ribs, concrete plate and studs connecting OSD and concrete plate. The OSD can act as framework for concrete plate and contribute to load bearing capacity at the same time, which could save construction time. Compared with conventional OSD system, this new type of composite bridge deck can also improve fatigue performance. Considering that this type of composite deck is not yet applied in practical engineering and its mechanical performance is not revealed in previous literatures, two full-scale specimens were designed and manufactured in this research. The mechanical performance, particularly, bending capacity in positive and negative region was carefully tested and analyzed. The load-deflection curve, load-slip relation, strain distribution in concrete and steel were obtained. The test results showed that the plastic performance of this kind of composite bridge deck was satisfying and the bending capacity was high.

关键词: bending performance     composite bridge deck     T-shaped steel ribs    

Surface-tailoring chlorine resistant materials and strategies for polyamide thin film composite reverse

《化学科学与工程前沿(英文)》 2022年 第16卷 第5期   页码 564-591 doi: 10.1007/s11705-021-2109-z

摘要: Polyamide thin film composite membranes have dominated current reverse osmosis market on account of their excellent separation performances compared to the integrally skinned counterparts. Despite their very promising separation performance, chlorine-induced degradation resulted from the susceptibility of polyamide toward chlorine attack has been regarded as the Achilles’s heel of polyamide thin film composite. The free chlorine species present during chlorine treatment can impair membrane performance through chlorination and depolymerization of the polyamide selective layer. From material point of view, a chemically stable membrane is crucial for the sustainable application of membrane separation process as it warrants a longer membrane lifespan and reduces the cost involved in membrane replacement. Various strategies, particularly those involved membrane material optimization and surface modifications, have been established to address this issue. This review discusses membrane degradation by free chlorine attack and its correlation with the surface chemistry of polyamide. The advancement in the development of chlorine resistant polyamide thin film composite membranes is reviewed based on the state-of-the-art surface modifications and tailoring approaches which include the in situ and post-fabrication membrane modifications using a broad range of functional materials. The challenges and future directions in this field are also highlighted.

关键词: reverse osmosis     polyamide     thin film composite membranes     chlorine resistance     surface modification    

Water film coated composite liquid metal marble and its fluidic impact dynamics phenomenon

Yujie DING,Jing LIU

《能源前沿(英文)》 2016年 第10卷 第1期   页码 29-36 doi: 10.1007/s11708-015-0388-0

摘要: A composite liquid metal marble made of metal droplet coated with water film was proposed and its impact dynamics phenomenon was disclosed. After encapsulating the liquid metal into water droplets, the fabricated liquid marble successfully avoided being oxygenized by the metal fluid and thus significantly improved its many physical capabilities such as surface tension modification and shape control. The striking behaviors of the composite liquid metal marbles on a substrate at room temperature were experimentally investigated in a high speed imaging way. It was disclosed that such marbles could disintegrate, merge, and even rebound when impacting the substrate, unlike the existing dynamic fluidic behaviors of liquid marble or metal droplet. The mechanisms lying behind these features were preliminarily interpreted. This fundamental finding raised profound multiphase fluid mechanics for understanding the complex liquid composite which was also critical for a variety of practical applications such as liquid metal jet cooling, inkjet printed electronics, 3D printing or metal particle fabrication etc.

关键词: liquid metal marble     metallic droplet     composite fluid     impact dynamics     multiphase fluid mechanics    

Numerical simulation of squat reinforced concrete wall strengthened by FRP composite material

Ali KEZMANE,Said BOUKAIS,Mohand Hamizi

《结构与土木工程前沿(英文)》 2016年 第10卷 第4期   页码 445-455 doi: 10.1007/s11709-016-0339-9

摘要: The advanced design rules and the latest known earthquakes, have imposed a strengthening of reinforced concrete structures. Many research works and practical achievements of the application of the external reinforcement by using FRP composite materials have been particularly developed in the recent years. This type of strengthening seems promising for the seismic reinforcement of buildings. Among of the components of structures that could affect the stability of the structure in case of an earthquake is the reinforced concrete walls, which require in many cases a strengthening, especially in case where the diagonal cracks can be developed. The intent of this paper is to present a numerical simulation of squat reinforced concrete wall strengthened by FRP composite material (carbon fiber epoxy). The intent of this study is to perform finite element model to investigate the effects of such reinforcement in the squat reinforced concrete walls. Taking advantage of a commercial finite element package ABAQUS code, three-dimensional numerical simulations were performed, addressing the parameters associated with the squat reinforced concrete walls. An elasto-plastic damage model material is used for concrete, for steel, an elastic-plastic behavior is adopted, and the FRP composite is considered unidirectional and orthotropic. The obtained results in terms of displacements, stresses, damage illustrate clearly the importance of this strengthening strategy.

关键词: simulation     strengthening     reinforced concrete wall     squat wall     FRP composite material     damage     Abaqus    

玻璃纤维复合材料新生态复合技术

回显权

《中国工程科学》 2002年 第4卷 第4期   页码 93-94

摘要:

现代结构材料正向复合化方向发展。复合材料发展的关键在于开创低成本、高可靠性的复合技术。 将玻璃纤维复合材料由传统的后期复合改为新生态的早期复合,可降低复合成本和提高可靠性。

关键词: 复合材料     早期复合     单纤维复合     纤维力学效应     界面效应     树脂薄膜效应    

标题 作者 时间 类型 操作

A novel strategy for the construction of silk fibroin–SiO composite aerogel with enhanced mechanical

期刊论文

Precast steel–UHPC lightweight composite bridge for accelerated bridge construction

Shuwen DENG, Xudong SHAO, Xudong ZHAO, Yang WANG, Yan WANG

期刊论文

Technological development and engineering applications of novel steel-concrete composite structures

Jianguo NIE, Jiaji WANG, Shuangke GOU, Yaoyu ZHU, Jiansheng FAN

期刊论文

Factors affecting photocatalytic performance through the evolution of the properties due to the phase transition from NaBiO·2HO to BiO

期刊论文

Deep eutectic solvent inclusions for high- composite dielectric elastomers

期刊论文

An antibiotic composite electrode for improving the sensitivity of electrochemically active biofilm biosensor

期刊论文

Structural optimization of filament wound composite pipes

Roham RAFIEE; Reza SHAHZADI; Hossein SPERESP

期刊论文

Progressive failure analysis of notched composite plate by utilizing macro mechanics approach

期刊论文

Bending and rotational behaviour of semi-continuous composite beams

WANG Jingfeng, LI Guoqiang

期刊论文

Experimental study on flexural behavior of ECC/RC composite beams with U-shaped ECC permanent formwork

Zhi QIAO, Zuanfeng PAN, Weichen XUE, Shaoping MENG

期刊论文

Bending performance of composite bridge deck with T-shaped ribs

Qingtian SU, Changyuan DAI, Xu JIANG

期刊论文

Surface-tailoring chlorine resistant materials and strategies for polyamide thin film composite reverse

期刊论文

Water film coated composite liquid metal marble and its fluidic impact dynamics phenomenon

Yujie DING,Jing LIU

期刊论文

Numerical simulation of squat reinforced concrete wall strengthened by FRP composite material

Ali KEZMANE,Said BOUKAIS,Mohand Hamizi

期刊论文

玻璃纤维复合材料新生态复合技术

回显权

期刊论文